This is the full list of all of England opponents by number of matches played (P  W  D  L  F  A  Pts%  W/L)

110
Scotland P 110 H 55 A 55 N 0
30 November 1872 - 17 November 1999		        

101
Wales P 101 H 51 A 50 N 0
18 January 1879 - 6 September 2011		        

 

61
Ireland (combined) P 61 H 30 A 31 N 0
18 February 1882 - 11 November 1953		        

 

37
Ireland, Northern P 37 H 20 A 17 N 0
2 October 1954 - 7 September 2005		        

Outside the home nations...

29
France P 29 H 10 A 15 N 4
10 May 1923 - 11 June 2012		        

 

24
Brazil P 24 H 11 A 5 N 8
9 May 1956 - 6 February 2013		   Italy P 24 H 8 A 11 N 5
13 May 1933 - 15 August 2012
Sweden P 24 H 9 A 13 N 2
21 May 1923 - 14 November 2012		        

 

23
Spain P 23 H 10 A 11 N 2
15 May 1929 - 12 November 2011		        

 

22

Hungary P 22 H 10 A 11 N 1
10 June 1908 - 11 August 2010		   Portugal P 22 H 9 A 9 N 4
25 May 1947 - 1 July 2006
Switzerland P 22 H 9 A 12 N 1
20 May 1933 - 4 June 2011		        

21

Belgium P 21 H 6 A 11 N 4
21 May 1921 - 2 June 2012		        

 

19
Netherlands P 19 H 10 A 7 N 2
18 May 1935 - 29 February 2012		        

18
Austria P 18 H 6 A 11 N 1
6 June 1908 - 16 November 2007		  

Denmark P 18 H 7 A 9 N 2
26 September 1948 - 9 February 2011
Poland P 18 H 8 A 9 N 1
5 January 1966 - 17 October 2012		        

16
Germany, West (FDR) P 16 H 6 A 6 N 4
1 December 1954 - 4 July 1990		        

 

14

Argentina P 14 H 6 A 2 N 6
9 May 1951 - 12 November 2005		   Ireland, Republic of P 14 Ab 1 H 6 A 6 N 2
30 September 1946 - 15 February 1995
Yugoslavia P 14 H 7 A 6 N 1
18 May 1939 - 13 December 1989		        

12
Czechoslovakia P 12 H 5 A 5 N 2
16 May 1934 - 25 March 1992		   Germany (combined) P 12 H 5 A 4 N 3
10 May 1930 - 28 June 2010

11

Finland P 11 H 3 A 8 N 0
20 May 1937 - 24 March 2001		   Romania P 11 H 4 A 4 N 3
24 May 1939 - 20 June 2000
USSR P 11 H 4 A 3 N 4
18 May 1958 - 21 May 1991		        

 

10
Bulgaria P 10 H 5 A 4 N 1
7 June 1962 - 2 September 2011		   Norway P 10 H 4 A 6 N 0
14 May 1937 - 11 October 1995
Turkey P 10 H 5 A 5 N 0
14 November 1984 - 11 October 2003		   Uruguay P 10 H 5 A 4 N 1
31 May 1953 - 1 March 2006
USA P 10 H 2 A 6 N 2
29 June 1950 - 12 June 2010		        

 

9

Greece P 9 H 5 A 4 N 0
21 April 1971 - 16 August 2006		   Luxembourg P 9 H 4 A 5 N 0
21 May 1927 - 4 September 1999
Mexico P 9 H 5 A 3 N 1
24 May 1959 - 24 May 2010		        

 

8
             

 

7
Croatia P 7 H 4 A 2 N 1
24 April 1996 - 9 September 2009		        

 

6
Australia P 6 H 1 A 5 N 0
31 May 1980 - 12 February 2003		   Ukraine P 6 H 4 A 2 N 0
31 May 2000 - 11 September 2012

 

5
Chile P 5 H 2 A 2 N 1
25 June 1950 - 11 February 1998		   Colombia P 5 H 2 A 1 N 2
20 May 1970 - 31 May 2005

 

4
Albania P 4 H 2 A 2 N 0
8 March 1989 - 5 September 2001		   Andorra P 4 H 2 A 2 N 0
2 September 2006 - 10 June 2009
Cameroon P 4 H 2 A 0 N 2
1 July 1990 - 26 May 2002		   GDR (East Germany) P 4 H 2 A 2 N 0
2 June 1963 - 12 September 1984
Israel P 4 H 1 A 3 N 0
26 February 1986 - 8 September 2007		   Macedonia FYR P 4 H 2 A 2 N 0
16 October 2002 - 7 October 2006
San Marino P 4 H 2 A 2 N 0
17 February 1993 - 22 March 2013		        

 

3
Egypt P 3 H 1 A 1 N 1
29 January 1986 - 3 March 2010		   Japan P 3 H 2 A 0 N 1
2 June 1995 - 30 May 2010
Malta P 3 H 1 A 2 N 0
3 February 1971 - 3 June 2000		   Moldova P 3 H 1 A 2 N 0
1 September 1996 - 7 September 2012
Montenegro P 3 H 1 A 2 N 0
12 October 2010 - 26 March 2013		   Paraguay P 3 H 1 A 0 N 2
18 June 1986 - 10 June 2006
Slovakia P 3 H 2 A 1 N 0
12 October 2002 - 28 March 2009		        

 

2
Azerbaijan P 2 H 1 A 1 N 0
13 October 2004 - 30 March 2005		   Belarus P 2 H 1 A 1 N 0
15 October 2008 - 14 October 2009
Cyprus P 2 H 1 A 1 N 0
16 April 1975 - 11 May 1975		   Czech Republic P 2 H 2 A 0 N 0
18 November 1998 - 20 August 2008
Ecuador P 2 H 0 A 1 N 1
24 May 1970 - 25 June 2006		   Estonia P 2 H 1 A 1 N 0
6 June 2007 - 13 October 2007
Georgia P 2 H 1 A 1 N 0
9 November 1996 - 30 April 1997		   Iceland P 2 H 1 A 1 N 0
2 June 1982 - 5 June 2004
Kazakhstan P 2 H 1 A 1 N 0
11 October 2008 - 6 June 2009		   Liechtenstein P 2 H 1 A 1 N 0
29 March 2003 - 10 September 2003
Morocco P 2 H 0 A 1 N 1
6 June 1986 - 27 May 1998		   New Zealand P 2 H 0 A 2 N 0
3 June 1991 - 8 June 1991
Nigeria P 2 H 1 A 0 N 1
16 November 1994 - 12 June 2002		   Peru P 2 H 0 A 2 N 0
17 May 1959 - 20 May 1962
Rest of the World P 2 H 2 A 0 N 0
21 October 1953 - 23 October 1963		   Russia P 2 H 1 A 1 N 0
12 September 2007 - 17 October 2007
Saudi Arabia P 2 H 1 A 1 N 0
16 November 1988 - 23 May 1998		   Slovenia P 2 H 1 A 0 N 1
5 September 2009 - 23 June 2010
South Africa P 2 H 1 A 1 N 0
24 May 1997 - 22 May 2003		   Trinidad & Tobago P 2 H 0 A 1 N 1
15 June 2006 - 1 June 2008
Tunisia P 2 H 0 A 1 N 1
2 June 1990 - 15 June 1998		        

 

1
Algeria P 1 H 0 A 0 N 1
18 June 2010		   Bohemia P 1 H 0 A 1 N 0
13 June 1908
Canada P 1 H 0 A 1 N 0
24 May 1986		   China P 1 H 0 A 1 N 0
23 May 1996
CIS P 1 H 0 A 1 N 0
29 April 1992		   Ghana P 1 H 1 A 0 N 0
29 March 2011
Jamaica P 1 H 1 A 0 N 0
3 June 2006		   Korea Republic (North) P 1 H 0 A 1 N 0
21 May 2002
Kuwait P 1 H 0 A 0 N 1
25 June 1982		 Malaysia P 1 H 0 A 1 N 0
12 June 1991
Rest of Europe P 1 H 1 A 0 N 0
26 October 1938		   Serbia and Montenegro P 1 H 1 A 0 N 0
3 June 2003

 

Not yet played...
this is a list of FIFA-affiliated countries that England have yet to play, in order of highest ranked, as of December 2012.
Top 50 - Côte d'Ivoire (14), Mali (25), Bosnia & Herzegovina (27), Zambia (34), Serbia (38), Haiti (39), Bolivia (=42), Gabon (=42).
51 to 100 - Panama, Central African Republic, Libya, Venezuela, Honduras, Iran, Guinea, Sierra Leone, Costa Rica, Uzbekistan, Cape Verde Islands, Togo, Armenia, Benin, Senegal, Equatorial Guinea, Guatemala, Angola, Uganda, Burkina Faso, Iraq, Dominican Republic, Jordan, Oman, United Arab Emirates, Qatar, Korea DPR, Cuba.
 101 to 208 - Sudan, Zimbabwe, El Salvador, Burundi, Niger, Latvia, Congo DR, New Caledonia, Congo, Ethiopia, Malawi, Liberia, Mozambique, Suriname, Antigua & Barbuda, Lithuania, Bahrain, São Tomé e Príncipe, Botswana, Namibia, St. Kitts & Nevis, Guyana, St. Vincent & Grenadines, Lebanon, Turkmenistan, Tanzania, Vietnam, Puerto Rico, Kenya, Rwanda, Tajikistan, Thailand, Grenada, Tahiti, Chad, Gambia, Barbados, Syria, Nicaragua, Philippines, St Lucia, Solomon Islands, Aruba, Palestine, Faroe Islands, Singapore, Indonesia, Bermuda, Lesotho, Maldives, Dominica, Myanmar, Hong Kong, Yemen, Vanuatu, India, Belize, Bangladesh, Chinese Taipei, Fiji, Laos, Nepal, Samoa, Bahamas, Guinea-Bissau, Montserret, Curaçao, Swaziland, Madagascar, Mongolia, Guam, Brunei Darussalam, Timor-Leste, Cambodia, Tonga, Afghanistan, US Virgin Islands, Papua New Guinea, Pakistan, Sri Lanka, British Virgin Islands, Cayman Islands, American Samoa, Comoros, Somalia, Eritrea, Seychelles, Macau, Kyrgyzstan, South Sudan, Cook Islands, Djibouti, Mauritius, Anguilla, Mauritania, Bhutan, Turks & Caicos Islands.

 

Total

30 November 1872 - 26 March 2013

  

P 918 W 521 D 223 L 174 F 2036 A 918 - 68.9% +347